2021

Masel, R. I.*; Liu, Z.; Yang, H.; Kaczur, J. J.; Carrillo, D.; Ren, S.; Salvatore, D.; Berlinguette, C. P. “An Industrial Perspective on Catalysts for Low-Temperature CO2 Electrolysis.” Nat. Nanotechnol. 2021, 16, 118-128. DOI: 10.1038/s41565-020-00823-x

Salvatore D. A.; Gabardo, C. M.; Reyes, A.; O’Brien, C. P.; Holdcroft, S.; Pintauro, P.; Bahar, B.; Hickner, M.; Bae, C.; Sinton, D.; Sargent, E. H.*; Berlinguette, C. P.* “Designing Anion Exchange Membranes for CO2 Electrolysers.” Nat. Energy 2021. DOI: 10.1038/s41560-020-00761-x

Kurimoto, A.; Jansonius, R. P.; Huang, A.; Marelli, A. M.; Dvorak, D. J.; Hunt, C.; Berlinguette, C. P.* “Physical Separation of H2 Activation from Hydrogenation Chemistry Reveals the Specific Role of Secondary Metal Catalysts.” Angew. Chem. Int. Ed. 2021. DOI: 10.1002/anie.202017082

Huang, A.; Cao, Y.; Delima, R. S.; Ji, T.; Jansonius, R. P.; Johnson, N. J. J.; Hunt, C.; He, J.; Kurimoto, A.; Zhang, Z.; Berlinguette, C. P.* “Electrolysis Can Be Used to Resolve Hydrogenation Pathways at Palladium Surfaces in a Membrane Reactor.” JACS Au. 2021, 1 (3), 336–343. DOI: 10.1021/jacsau.0c00051

2020

Kellett, C. W.; Berlinguette, C. P.* “Defining Direct Orbital Pathways for Intermolecular Electron Transfer Using Sensitized Semiconducting Surfaces.” Inorg. Chem. 2020, 59 (20), 14696-14705. DOI: 10.1021/acs.inorgchem.0c02251

Goldman, M.; Lees, E. W.; Prieto, P. L.; Mowbray, B. A. W.; Weekes, D. M.; Reyes, A.; Li, T.; Salvatore, D. A.; Smith, W. A.; Berlinguette, C. P. Electrochemical Reactors. in Carbon Dioxide Electrochemistry: Homogeneous and Heterogeneous Catalysis. 408-432 (The Royal Society of Chemistry, 2021DOI: 10.1039/9781788015844

Proppe, A. H.; Li, Y. C.; Aspuru-Guzik, A.; Berlinguette, C. P.; Chang, C. J.; Cogdell, R.; Doyle, A. G.; Flick, J.; Gabor, N. M.; Grondelle, R. van; Hammes-Schiffer, S.; Jaffer, S. A.; Kelley, S. O.; Leclerc, M.; Leo, K.; Mallouk, T. E.; Narang, P.; Schlau-Cohen, G. S.; Scholes, G. D.; Vojvodic, A.; Yam, V. W-W.; Yang, J. Y.; Sargent, E. H.* “Bioinspiration in Light Harvesting and Catalysis.” Nat. Rev. Mater. 20205, 828-846DOI: 10.1038/s41578-020-0222-0

Lees, E. W.; Mowbray, B. A. W.; Salvatore, D. A.; Simpson, G. L.; Dvorak, D. J.; Ren, S.; Chau, J.; Milton, K. L.; Berlinguette, C. P.* “Linking Gas Diffusion Electrode Composition to CO2 Reduction in a Flow Cell.” J. Mat. Chem. A. 2020, 8, 19493-19501DOI: 10.1039/d0ta03570j

Zhang, Z.; Melo, L.; Jansonius, R. P.; Habibzadeh, F.; Grant, E. R.; Berlinguette, C. P.* “pH Matters When Reducing CO2 in an Electrochemical Flow Cell.” ACS Energy Lett. 2020, 5 (10), 3101-3107. DOI: 10.1021/acsenergylett.0c01606

Kurimoto, A.; Sherbo, R. S.; Cao, Y.; Loo, N. W. X.; Berlinguette, C. P.* “Electrolytic Deuteration of Unsaturated Bonds Without Using D2.” Nat. Catal. 2020. DOI: 10.1038/s41929-020-0488-z

Taherimakhsousi, N.; MacLeod, B. P.; Parlane, F. G. L.; Morrissey, T. D.; Booker, E. P.; Dettelbach, K. E.; Berlinguette, C. P.* “Quantifying Defects in Thin Films Using Machine Vision.” NPJ Comput. Mater. 2020, 6 (111). DOI: 10.1038/s41524-020-00380-w

Jansonius, R. P.; Kurimoto, A.; Marelli, A. M.; Huang, A.; Sherbo, R. S.; Berlinguette, C. P.* “Hydrogenation Without H2 Using a Palladium Membrane Flow Cell.” Cell Rep. Phys. Sci. 2020, 1 (7). DOI: 10.1016/j.xcrp.2020.100105

Kellett, C. W.; Kennepohl, P.; Berlinguette, C. P.* “π Covalency in the Halogen Bond.” Nat. Commun. 2020, 11, 3310. DOI: 10.1038/s41467-020-17122-7

Lees, E. W.; Goldman, M.; Fink, A. G.; Dvorak, D. J.; Salvatore, D. A.; Zhang, Z.; Loo, N. W. X.; Berlinguette, C. P.* “Electrodes Designed for Converting Bicarbonate into CO.” ACS Energy Lett. 2020, 5 (7), 2165-2173. DOI: 10.1021/acsenergylett.0c00898

Torbensen, K.; Joulié, D.; Ren, S.; Wang, M.; Salvatore, D. A.; Berlinguette, C. P.*; Robert, M.* “Molecular Catalysts Boost the Rate of Electrolytic CO2 Reduction.” ACS Energy Lett. 2020, 5 (5), 1512-1518. DOI: 10.1021/acsenergylett.0c00536

Salvatore, D. A.; Berlinguette, C. P.* “Voltage Matters When Reducing CO2 in an Electrochemical Flow Cell.” ACS Energy Lett. 2020, 5 (1), 215-220. DOI: 10.1021/acsenergylett.9b02356

Jansonius, R. P.; Schauer, P. A.; Dvorak, D. J.; MacLeod, B. P.; Fork, D. K.; Berlinguette, C. P.* “Strain Influences the Hydrogen Evolution Activity and Absorption Capacity of Palladium.” Angew. Chem. 2020, 59 (29). DOI: 10.1002/anie.202005248

Reyes, A.; Jansonius, R. P.; Mowbray, B. A. W.; Cao, Y.; Chau, J.; Wheeler, D.; Dvorak, D. J.; Berlinguette, C. P.* “Managing Hydration at the Cathode Enables Efficient CO2 Electrolysis at Commercially Relevant Current Densities.” ACS Energy Lett. 2020, 5 (5), 1612-1618.
DOI: 10.1021/acsenergylett.0c00637

MacLeod, B. P.; Parlane, F. G. L.; Morrissey, T. D.; Häse, F.; Roch, L.; Dettelbach, K. E.; Moreira, R.; Yunker, L. P. E.; Rooney, M. B.; Deeth, J. R.; Lai, V.; Ng, G. J.; Situ, H.; Zhang, R. H.; Elliott, M. S.; Haley, T. H.; Dvorak, D. J.;  Aspuru-Guzik, A.*; Hein, J. E.*; Berlinguette, C. P.* “Self-Driving Laboratory for Accelerated Discovery of Thin-Film Materials.” Sci. Adv. 2020, 6 (20), eaaz8867. DOI: 10.1126/sciadv.aaz8867

Li, T.; Mo, J. Y; Weekes, D. M.; Dettelbach, K. E.; Jansonius, R.; Sammis, G. M.*; Berlinguette, C. P.* “Photoelectrochemical Decomposition of Lignin Model Compound on a BiVO4 Photoanode.” ChemSusChem 2020, 13 (14), 3622-3626. DOI: 10.1002/cssc.202001134

Suntrup, L.; Stein, F.; Klein, J.; Wilting, A.; Parlane, F. G. L.; Brown, C.; Berlinguette, C. P.*; Siewert, I.*; Sarkar, B.* “Rhenium Complexes of Pyridyl-Mesoionic Carbenes: Photochemical Properties and Electrocatalytic CO2 Reduction.” Inorg. Chem. J. 2020, 59 (7), 4215-4227DOI: 10.1021/acs.inorgchem.9b02591

2019

Delima, R. S.; Sherbo, R. S.; Dvorak, D. J.; Kurimoto, A.; Berlinguette, C. P.* “Supported Palladium Membrane Reactor Architecture for Electrocatalytic Hydrogenation.” J. Mater. Chem. A. 2019, 7 (46), 26586–26595. DOI: 10.1039/C9TA07957B

Cao, Y.; Li, Y.; Morrissey, T.; Lam, B.; Patrick, B. O.; Dvorak, D. J.; Xia, Z.; Kelly, T. L.*; Berlinguette, C. P.* “Dopant-free Molecular Hole Transport Material that Mediates a 20% Power Conversion Efficiency in a Perovskite Solar Cell.” Energy Environ. Sci. 2019, 12 (12), 3502-3507. DOI: 10.1039/C9EE02983D 

Forward, R.; Chen, K.; Weekes, D. M.; Dvorak, D. J.; Cao, Y.; Berlinguette, C. P.* “Protocol for Quantifying the Doping of Organic Hole-Transport Materials.” ACS Energy Lett. 2019, 4 (10), 2547-2551. DOI: 10.1021/acsenergylett.9b01766 

Johnson, N. J. J.; Lam, B.; Sherbo, R. S.; Fork, D. K.; Berlinguette, C. P.* “Ligands Affect Hydrogen Absorption and Desorption by Palladium Nanoparticles.” Chem. Mater. 2019, 31 (21), 8679-8684. DOI: 10.1021/acs.chemmater.9b02193

Wheeler, D. G.; Virca, C. N.; Berlinguette, C. P.* “Analytical Electrolyzer Enabling Operando Characterization of Flow Plates.” Rev. Sci. Instrum. 2019, 90 (7), 074103. DOI: 10.1063/1.5053600

Wang, M.; Torbensen, K.; Salvatore, D. A.; Ren, S.; Joulié, D.; Dumoulin, F.; Mendoza, D.; Lassalle-Kaiser, B.; Isci, U.; Berlinguette, C. P.; Robert, M.* “CO2 Electrochemical Catalytic Reduction with a Highly Active Cobalt Phthalocyanine.” Nat. Commun. 2019, 10, 3602. DOI: 10.1038/s41467-019-11542-w

Ren, S.; Joulié, D.; Salvatore, D. A.; Torbensen, K.; Wang, M.; Robert, M.; Berlinguette, C. P.* “Molecular Electrocatalysts can Mediate Fast, Selective CO2 Reduction in a Flow Cell.” Science 2019, 365 (6451), 367-369. DOI: 10.1126/science.aax4608

Tabor, D.; Chiykowski, V. A.; Pascal, F.; Yang, C.; Dvorak, D. J.; Berlinguette, C. P.; Aspuru-Guzik, A.* “Design Rules for High Mobility Xanthene-Based Hole Transport Materials.” Chem. Sci. 2019, 10 (36), 8360-8366. DOI:10.1039/C9SC01491H

Li, T.; Lees, E. W.; Goldman, M.; Salvatore, D. A.; Weekes, D. M.; Berlinguette, C. P.* “Electrolytic Conversion of Bicarbonate into CO in a Flow Cell.” Joule 20193 (6), 1487-1497DOI:10.1016/j.joule.2019.05.021

Berlinguette, C. P.*; Chiang, Y.-M.; Munday, J. N.; Schenkel, T.; Fork, D. K.; Koningstein, R.; Trevithick, M. D. “Revisiting the Cold Case of Cold Fusion.” Nature 2019, 570, 45-51. DOI:10.1038/s41586-019-1256-6

MacLeod, B. P.; Fork, D. K.; Lam, B.; Berlinguette, C. P.* “Calorimetry Under Non-Ideal Conditions Using System Identification.” J. Therm. Anal. Calorim. 2019138, 3139–3157DOI: 10.1007/s10973-019-08271-z

Sherbo, R. S.; Kurimoto, A.; Brown, C. M.; Berlinguette, C. P.* “Efficient Electrocatalytic Hydrogenation with a Palladium Membrane Reactor.” J. Am. Chem. Soc. 2019, 141 (19), 7815-7821DOI: 10.1021/jacs.9b01442

Jansonius, R. P.; Reid, L. M.; Virca, C. N.; Berlinguette, C. P.* “Strain Engineering Electrocatalysts for Selective CO2 Reduction.” ACS Energy Lett. 2019, 4 (4), 980-986. DOI: 10.1021/acsenergylett.9b00191

Johnson, N. J. J.; Lam, B.; MacLeod, B. P.; Sherbo, R. S.; Moreno-Gonzalez, M.; Fork, D. K.; Berlinguette, C. P.* Facets and Vertices Regulate Hydrogen Uptake and Release in Palladium Nanocrystals. Nat. Mater. 2019, 18, 454-458DOI: 10.1038/s41563-019-0308-5

Piechota, E. J.; Sampaio, R. N.; Troian-Gautier, L.; Maurer, A. B.; Berlinguette, C. P.; Meyer, G. J.* “Entropic Barriers Determine Adiabatic Electron Transfer Equilibrium.” J. Phys. Chem. C, 2019, 123 (6), 3416-3425. DOI: 10.1021/acs.jpcc.8b11815

Dettelbach, K. E.; He, J.; Johnson, N. J.; Huang, A.; Bottomley, A.; Lam, B.; Salvatore, D. A.; Berlinguette, C. P.* “Kinetic Phases of Ag-Cu Alloy Films are Accessible through Photodeposition.” J. Mater. Chem. A, 2019, 7 (2), 711-715DOI: 10.1039/c8ta10138h

2018

Cheng, W.; Moreno-Gonzalez, M.; Krzyszkowski, C.; Dvorak, D. J.; Weekes, D. M.; Tam, B.; Berlinguette, C. P.* “Solution-Deposited Solid-State Electrochromic Windows.” iScience 2018, 10, 80-86DOI: 10.1016/j.isci.2018.11.014

Kellett, C. W.; Swords, W. B.; Turlington, M. D.; Meyer, G. J.*; Berlinguette, C. P.* “Resolving Orbital Pathways for Intermolecular Electron Transfer.Nat. Commun. 2018, 9, 4916. DOI: 10.1038/s41467-018-07263-1

He, J.; Huang, A.; Johnson, N. J. J.; Dettelbach, K. E.; Weekes, D. M.; Cao, Y.; Berlinguette, C. P.* “Stabilizing Copper for CO2 Reduction in Low-Grade Electrolyte.” Inorg. Chem. 2018, 57 (23), 14624-14631DOI: 10.1021/acs.inorgchem.8b02311

Chiykowski, V.; Cao, Y.; Tan, H.; Tabor, D. P.; Sargent, E. H.; Aspuru-Guzik, A.; Berlinguette, C. P.* “Precise Control of Thermal and Redox Properties of Organic Hole-Transport Materials.Angew. Chem. Int. Ed. 2018, 57 (47), 15529-15533DOI: 10.1002/anie.201810809 Hot paper!

Chen, K. Y.; Schauer, P. A.; Patrick, B. O.; Berlinguette, C. P.* Correlating Cobalt Redox Couples to Photovoltage in the Dye-sensitized Solar Cell. Dalton Trans. 2018, 47 (34), 11942-11952. DOI: 10.1039/C8DT01921E

Sampaio, R. N.; Piechota, E. J.; Troian-Gautier, L.; Hu, K.; Schauer, P. A.; Blair, A. D.; Berlinguette, C. P.;  Meyer, G. J.* “Kinetics Teach That Electronic Coupling Lowers the Free Energy Change that Accompanies Electron Transfer.Proc. Nat. Acad. Sci. USA 2018, 115 (28), 7248-7253. DOI: 10.1073/pnas.1722401115

Sherbo, R. S.; Delima, R. S.; Chiykowski, V. A.; MacLeod, B. P.; Berlinguette, C. P.* Complete Electron Economy by Pairing Electrolysis with Hydrogenation. Nat. Catal. 2018, 1, 501-507. DOI: 10.1038/s41929-018-0083-8

Sherbo, R. S.; Moreno-Gonzalez, M.; Johnson, N. J. J.; Dvorak, D. J.; Fork, D. K.; Berlinguette, C. P.* Accurate Coulometric Quantification of Hydrogen Absorption in Palladium Nanoparticles and Thin Films. Chem. Mater. 2018, 30 (12), 3963-3970. DOI: 10.1021/acs.chemmater.8b01324

Reid, L. M.; Li, T.; Cao, Y.; Berlinguette, C. P.* “Organic Chemistry at Anodes and Photoanodes.” Sus. Energy Fuels. 2018, 2 (9), 1905-1927. DOI: 10.1039/C8SE00146D

Piechota, E.; Troian-Gautier, L.; Sampaio, R.; Brennaman, K.; Hu, K.; Berlinguette, C. P.; Meyer, G. J.* “Optical Intramolecular Electron Transfer in Opposite Directions through the Same Bridge that Follows Different Pathways.” J. Am. Chem. Soc. 2018, 140 (23), 7176-7186. DOI: 10.1021/jacs.8b02715

Cheng, W.; He, J.; Dettelbach, K. E.; Johnson, N. J.; Sherbo, R. S.; Berlinguette, C. P.* “Photodeposited Amorphous Oxide Films for Electrochromic Windows.” Chem 2018, 4 (4), 821-832. DOI: 10.1016/j.chempr.2017.12.030

Weekes, D. M.; Salvatore, D. A.; Reyes, A.; Huang, A.; Berlinguette, C. P.* “Electrolytic CO2 Reduction in a Flow Cell.” Acc. Chem. Res201851 (4), 910-918. DOI: 10.1021/acs.accounts.8b00010

Dettelbach, K. E.; Salvatore, D. A.; Bottomley, A.; Berlinguette, C. P.* “Tracking Precursor Degradation During the Photo-Induced Formation of Amorphous Metal Oxide Films.” J. Mater. Chem. A20186 (10), 4544-4549. DOI: 10.1039/C7TA10369G

He, J.; Johnson, N. J.; Huang, A.; Berlinguette, C. P.* “Electrocatalytic Alloys for CO2 Reduction.” ChemSusChem. 201811 (1), 48-57. DOI: 10.1002/cssc.201701825

Peña, B.; Owen, G. RH.; Dettelbach, K. E.; Berlinguette, C. P.* “Spin-Coated Epoxy Resin Embedding Technique Enables Facile SEM/FIB Thickness Determination of Porous Metal Oxide Ultra-Thin Films.” J. Microsc. 2018, 270 (3), 302-308. DOI: 10.1111/jmi.12683

Salvatore, D. A.; Weekes, D. M.; He, J.; Dettelbach, K. E.; Li, Y. C.; Mallouk,T. E*; Berlinguette, C. P.* “Electrolysis of Gaseous CO2 to CO in a Flow Cell with a Bipolar Membrane.” ACS Energy Lett20183 (1), 149-154. DOI: 10.1021/acsenergylett.7b01017

 

2017

Parlane, F. G. L.; Mustoe, C.; Kellett, C. W.; Simon, S. J.; Swords, W. B.; Meyer, G. J.; Kennepohl, P.; Berlinguette, C. P.* “Spectroscopic Detection of Halogen Bonding Resolves Dye Regeneration in the Dye-Sensitized Solar Cell.” Nat. Commun20178 (1761), 1-8. DOI: 10.1038/s41467-017-01726-7

Li, T.; Kasahara, T.; He, J.; Dettelbach, K. E.; Sammis, G. M.; Berlinguette, C. P.* “Photoelectrochemical Oxidation of Organic Substrates in Organic Media.” Nat. Commun20178, 390. DOI: 10.1038/s41467-017-00420-y

He, J.; Dettelbach, K. E.; Huang, A.; Berlinguette, C. P.* “Brass and Bronze Are Effective CO2 Reduction Electrocatalysts.” Angew. Chem. Int. Ed201756 (52), 16579-16582. DOI: 10.1002/anie.201709932

He, J.; Weekes, D. W.; Cheng, W.; Dettelbach, K. E.; Huang, A.; Li, T.; Berlinguette, C. P.* “Photodecomposition of Metal Nitrate and Chloride Compounds Yields Amorphous Metal Oxide Films.” J. Am. Chem. Soc. 2017139 (50), 18174-18177. DOI: 10.1021/jacs.7b11064

Dettelbach, K. E.; Kolbeck, M.; Huang, A.; He, J.; Berlinguette, C. P.* “Rapid Quantification of Film Thickness and Metal Loading for Electrocatalytic Metal Oxide Films.” Chem. Mater201729 (17), 7272-7277. DOI: 10.1021/acs.chemmater.7b01914

Zhang, C.; Zhang, X.; Daly, K.; Berlinguette, C. P.; Trudel, S.* “Water Oxidation Catalysis: Tuning the Electrocatalytic Properties of Amorphous Lanthanum Cobaltite through Calcium Doping.” ACS Catal20177 (9), 6385-6391. DOI: 10.1021/acscatal.7b02145

MacLeod, B.; Schauer, P. A.; Hu, K.; Lam, B.; Fork, D. K.; Berlinguette, C. P.* “High-Temperature High-Pressure Calorimeter for Studying Gram-Scale Heterogeneous Chemical Reactions.” Rev. Sci. Instrum. 2017, 88 (8), 084101. DOI:  10.1063/1.4999361

Li, T.; Cao, Y.; He, J.; Berlinguette, C. P.* “Electrolytic CO2 Reduction in Tandem with Oxidative Organic Chemistry.” ACS Cent. Sci20173 (7), 778-783. DOI: 10.1021/acscentsci.7b00207

Speck, F. D.; Dettelbach, K. E.; Sherbo, R. S.; Salvatore, D. A.; Huang, A.; Berlinguette, C. P.* “On the Electrolytic Stability of Iron-Nickel Oxides.” Chem 20172 (4), 590-597. DOI: 10.1016/j.chempr.2017.03.006

Chen, K. Y.; Du, C.; Patrick, D. O.; Berlinguette, C. P.* “High-Voltage Dye-Sensitized Solar Cells Mediated by [Co(2,2′-bipyrimidine)3]z.” Inorg. Chem. 201756 (5), 2383-2386. DOI: 10.1021/acs.inorgchem.7b00082

Chiykowski, V. A.; Lam, B.; Du, C.; Berlinguette, C. P.* “Comparative Analysis of Triarylamine and Phenothiazine Sensitizer Donor Units in Dye-Sensitized Solar Cells.” Chem. Commun. 201753 (15), 2367-2370. DOI: 10.1039/C6CC09178D

Chiykowski, V. A.; Lam, B.; Du, C.; Berlinguette, C. P.* “On How Electron Density Affects the Redox Stability of Phenothiazine Sensitizers on Semiconducting Surfaces.” Chem. Commun. 2017, 53 (17), 2547-2550. DOI: 10.1039/C6CC09992K

He, J.; Dettelbach, K. E.; Salvatore, D. A.; Li, T.; Berlinguette, C. P.* “High-Throughput Synthesis of Mixed-Metal Electrocatalysts for CO2 Reduction.” Angew. Chem. Int. Ed. 2017, 129 (22), 6164-6168. DOI: 10.1002/ange.201612038

Salvatore, D. A.; Peña, B.; Dettelbach, K. E.; Berlinguette, C. P.* “Photodeposited Ruthenium Dioxide Films for Oxygen Evolution Reaction Electrocatalysis.” J. Mater. Chem. A. 20175 (4), 29-33. DOI: 10.1039/C6TA09094J

2016

Li, Y. C.; Zhou, D.; Yan, Z.; Gonçalves, R. H.; Salvatore, D. A.; Berlinguette, C. P.; Mallouk, T. E.* “Electrolysis of CO2 to Syngas in Bipolar Membrane-Based Electrochemical Cells.” ACS Energy Lett. 2016, 1 (6), 1149-1153. DOI: 10.1021/acsenergylett.6b00475

Hudkins, J. R.; Wheeler, D. G.; Peña, B.; Berlinguette, C. P.* “Rapid Prototyping of Electrolyzer Flow Field Plates.” Energy Environ. Sci. 20169 (11), 3417-3423. DOI: 10.1039/C6EE01997H

Li, T.; He, J.; Peña, B.; Berlinguette, C. P.* “Exposure of WO3 Photoanodes to Ultraviolet Light Enhances Photoelectrochemical Water Oxidation.” ACS Appl. Mater. Interfaces 20168 (38), 25010–25013. DOI: 10.1021/acsami.6b08152

Simon, S. J. C.; Parlane, F. G. L.; Swords, W. B.; Kellett, C. W.; Du, C.; Lam, B.; Dean, R. K.; Hu, K.; Meyer, G. J.*; Berlinguette, C. P.* “Halogen Bonding Promotes Higher Dye-Sensitized Solar Cell Photovoltages.” J. Am. Chem. Soc2016138 (33), 10406-10409. DOI: 10.1021/jacs.6b06288

Hu, K.; Blair, A.; Piechota, E. B. S.; Schauer, P. A.; Sampaio, R.; Parlane, F. G.; Meyer, G. J.; Berlinguette, C. P.* “Kinetic Pathway for Interfacial Electron Transfer from a Semiconductor to a Molecule.” Nat. Chem. 20168, 853-859. DOI: 10.1038/nchem.2549

Smith, R. D. L.; Sherbo, R. S.; Dettelbach, K. E.; Berlinguette, C. P.* “On How Experimental Conditions Affect the Electrochemical Response of Disordered Nickel Oxyhydroxide Films.” Chem. Mat2016, 28 (16), 5635-5642 DOI: 10.1021/acs.chemmater.6b01420

Swords, W. B.; Simon, S. J. C.; Parlane, F. G. L.; Dean, R. K.; Kellett, C. W.; Hu, K.; Meyer, G. J.*; Berlinguette, C. P.* “Evidence for Interfacial Halogen Bonding.” Angew. Chem. Int. Ed2016, 55 (20), 5956–5960. DOI: 10.1002/anie.201510641

Li, T.; He, J.; Peña, B.; Berlinguette, C. P.* “Curing BiVO4 Photoanodes with Ultraviolet Light Enhances Photoelectrocatalysis.” Angew. Chem. Int. Ed2016, 55 (5), 1769-1772DOI: 10.1002/anie.201509567

Smith, R. D. L.; Berlinguette, C. P.* “Accounting for the Dynamic Oxidative Behavior of Nickel Anodes.” J. Am. Chem. Soc. 2016138 (5), 1561-1567. DOI: 10.1021/jacs.5b10728

Zhang, C.; Berlinguette, C. P.; Trudel, S. “Water Oxidation Catalysis: An Amorphous Quaternary Ba-Sr-Co-Fe Oxide as a Promising Electrocatalyst for the Oxygen-Evolution Reaction.” Chem. Commun2016, 52 (7), 1513-1516. DOI: 10.1039/C5CC09361A

2015

Salvatore, D. A.; Dettelbach, K. E.; Hudkins, J. R.; Berlinguette, C. P.* “Near-Infrared–Driven Decomposition of Metal Precursors Yields Amorphous Electrocatalytic Films.” Sci. Adv. 2015, 1 (2), e1400215. DOI: 10.1126/sciadv.1400215

Kurzman, A. J.; Dettelbach, K. E.; Martinolich, A. J.; Berlinguette, C. P.; Neilson, J. R. “Structural Characteristics and Eutaxy in the Photo-Deposited Amorphous Iron Oxide Oxygen Evolution Catalyst.” Chem. Mater. 201527 (9), 3462–3470. DOI: 10.1021/acs.chemmater.5b00878

Cuijuan, Z.; Fagan, R. D.; Smith, R. D. L.; Moore, S.; Berlinguette, C. P.*; Trudel, S.* “Mapping the Performance of Amorphous Ternary Metal Oxide Water Oxidation Catalysts Containing Aluminium.” J. Mat. Chem. A2015, 3 (2), 756-761. DOI: 10.1039/C4TA04495A

Asaduzzaman, A. M.*; Wasylenko, D.; Berlinguette, C. P.; Schreckenbach, G.* “Substitution Effects on the Water Oxidation of Ruthenium Catalysts: A Quantum-Chemical Look.” J. Phys. Chem. A. 2015, 119 (1), 242–250. DOI: 10.1021/jp5075847

Crandell, D.; Ghosh, S.; Berlinguette, C. P.*; Baik, M.-H.* “How a [CoIV-O]2+ Fragment Oxidizes Water: Involvement of a Biradicaloid [CoII-(·O·)]2+ Species in Forming the O–O Bond.” ChemSusChem 20158 (5), 844-852. DOI: 10.1002/cssc.201403024

Li, G.; Hu, K.; Robson, K.C.D.; Gorelsky, S. I.; Meyer, G. J.*; Berlinguette, C. P.*; Shatruk, M.* “Tris-Heteroleptic Ruthenium–Dipyrrinate Chromophores in a Dye-Sensitized Solar Cell.” Chem-Eur. J. 2015, 21 (5), 2173–2181. DOI: 10.1002/chem.201405261

2014

Li, G.; Yella, A.; Brown, D. G.; Gorelsky, S. I.; Nazeeruddin, M. K.; Grätzel, M.*; Berlinguette, C. P.*; Shatruk, M.* “Near-IR Photoresponse of Ruthenium Dipyrrinate Terpyridine Sensitizers in the Dye-Sensitized Solar Cells.” Inorg. Chem. 2014, 53 (11), 5417-5419. DOI: 10.1021/ic5006538

Hu, K.; Robson, K. C. D.; Berlinguette, C. P.*; Meyer, G. J.* “Donor–π–Acceptor Organic Hybrid TiO2 Interfaces for Solar Energy Conversion.” Thin Solid Films 2014560 (2), 49-54 (invited special issue on dye-sensitized solar cells) DOI: 10.1016/j.tsf.2013.08.113

Hu, K.; Severin, H.; Robson, K. C. D.; Koivisto, B. D.; Meyer, G. J.*; Berlinguette, C. P.* “Direct Spectroscopic Evidence for Constituent Heteroatoms Enhancing Charge Recombination at a TiO2—Ruthenium Dye Interface.” J. Phys.Chem. C2014118 (30), 17079−17089 (invited special issue celebrating the career of Prof Gratzel) DOI: 10.1021/jp500879p

Hu, K.; Robson, K.; Beauvilliers, E.; Schott, E.; Zarate, X.; Arratia-Perez, R.; Berlinguette, C. P.; Meyer, G. “Intramolecular and Lateral Intermolecular Hole Transfer at the Sensitized TiO2 Interface.” J. Am. Chem. Soc2014136 (3), 1034-1046. DOI: 10.1021/ja410647c

Zhang, C.; Trudel, S.*; Berlinguette, C. P.* “Water Oxidation Catalysis: Survey of Amorphous Binary Metal Oxide Films Containing Lanthanum and Late 3d Transition Metals.” Eur. J. Inorg. Chem2014 (4), 660-664. (invited; thematic issue on Water Oxidation CatalysisDOI: 10.1002/ejic.201300765

Smith, R. D. L.; Sporinova, B.; Fagan, R.; Sedach, P. A.; Trudel, S.*; Berlinguette, C. P.* “Facile Photochemical Preparation of Amorphous Iridium Oxide Films for Water Oxidation Catalysis.” Chem. Mat201426 (4), 1654-1659. DOI: 10.1021/cm4041715

Sinn, S.; Schulze, B.; Friebe, C.; Brown, D.; Jäger, M.; Kubel, J.; Dietzek, B; Berlinguette, C. P.*; Schubert, U.* “A Heteroleptic Bis(tridentate) Ruthenium(II) Platform Featuring an Anionic 1,2,3-Triazolate-Based Ligand for Application in the Dye-Sensitized Solar Cell.” Inorg. Chem201453 (3), 1637-1645. DOI: 10.1021/ic402701v

Sinn, S.; Friebe, C.; Schulze, B.; Brown, D.; Jäger, M.; Altuntas, E.; Dietzek, B; Kubel, J.; Guntner, O.; Berlinguette, C. P.*; Schubert, U.* “Physicochemical Analysis of Ruthenium(II) Sensitizers of 1,2,3-Triazole-Derived Mesoionic Carbine and Cyclometalating Ligands.” Inorg. Chem2014, 53 (4), 2083-2095. DOI: 10.1021/ic402702z

Wood, C. J.; Robson, K. C. D.; Horvath, R.; Calladine, J. A.; George, M. W.; Berlinguette, C. P.;* Gibson, E. A.* “Novel Triphenylamine-Modified Ruthenium(II) Terpyridine Complexes for Nickel Oxide-Based Cathodic Dye-Sensitized Solar Cells.” RSC Advances 20144 (11), 5782-5791. DOI: 10.1039/C3RA44690E

2013

Schulze, B.; Brown, D. G.; Robson, K. C. D.; Friebe, C.; Birckner, E.; Berlinguette, C. P.; Schubert, U. S. “Cyclometalated Ruthenium(II) Complexes Featuring Tridentate Click-Derived Ligands for DSSC Applications.” Chem. Eur. J201319 (42), 14171-14180. DOI: 10.1002/chem.201301440

Smith, R. D. L.; Prevot, M. S.; Fagan, R.; Sedach, P. A.; Trudel, S.*; Berlinguette, C. P.* “Water Oxidation Catalysis: Electrocatalytic Response to Metal Stoichiometry in Amorphous Metal Oxide Films Containing Iron, Cobalt, and Nickel.” J. Am. Chem. Soc., 2013135 (31), 11580-11586. DOI: 10.1021/ja403102j

Smith, R. D. L.; Prevot, M. S.; Fagan, R.; Zhang, Z.; Sedach, P. A.; Siu, M. K. J.; Berlinguette, C. P.* “Photochemical Route for Accessing Amorphous Metal-Oxide Materials for Heterogeneous Water Oxidation Catalysis.” Science 2013340 (6128), 60-63. (featured in >500 international media outlets) DOI: 10.1126/science.1233638

Brown, D. G; Schauer, P.; Berlinguette, C. P.* “Stabilization of Ruthenium Sensitizers to TiO2 Surfaces through Cooperative Binding Modes.” J. Am. Chem. Soc2013135 (5), 1692-1695. DOI: 10.1021/ja310965h

Pogozhev, D.; Bezdek, M.; Schauer, P. Berlinguette, C. P.;* “Ruthenium(II) Complexes Bearing a Naphthalimide Fragment: A Modular Dye Platform for the Dye-Sensitised Solar Cell.” Inorg. Chem201352 (6), 3001-3006. DOI: 10.1021/ic3024524

Robson, K. C. D.; Hu, K.; Johansson, P. G.; Meyer, G. J.,* Berlinguette, C. P.* “Atomic Level Resolution of Dye Regeneration in the Dye Sensitized Solar Cell.” J. Am. Chem. Soc2013135 (5), 1961-1971. DOI: 10.1021/ja311640f

Wasylenko, D. W.; Palmer, R. D.; Berlinguette, C. P.* “Homogeneous Water Oxidation Catalysts Containing a Single Metal Site.” Chem. Commun201349 (3), 218-227. (invited “Perspective”) DOI: 10.1039/C2CC35632E

Wasylenko, D. W.; Tatlock, H. M., Bhandari, L.; Gardinier, J. M., Berlinguette, C. P.* “Proton-Coupled Electron Transfer at a [Co-OHx]z Unit in Aqueous Media: Evidence for a Concerted Mechanism.” Chem. Sci20134 (2), 734-738. DOI: 10.1039/C2SC21419A

2012

Li. G.; Bomben, P. G.; Robson, K.; Gorelsky, S. I.*; Berlinguette, C. P.*; Shatruk, M. “Ru Complexes of Thienyl-Functionalized Dipyrrins in the Dye-Sensitized Solar Cell.” Chem. Commun2012, 48 (70), 8790. DOI: 10.1039/C2CC34311H

Brown, D. G.; Sanguantrakun, N.; Schulze B.; Schubert, U. S.;* Berlinguette, C. P.* “Bis(tridentate) Ruthenium–Terpyridine Complexes Featuring Microsecond Excited-State Lifetimes.” J. Am. ChemSoc2012134 (30), 12354–12357. DOI: 10.1021/ja3039536

Hu, K.; Robson, K. C. D.; Johansson, P. G.; Berlinguette, C. P.*; Meyer, G. J.* “Intramolecular Hole Transfer at Sensitized TiO2 Interfaces.” J. Am. Chem. Soc2012, 134 (20), 8352-8355DOI: 10.1021/ja3018175

Bomben, P. G.; Borau-Garcia, J.; Berlinguette, C. P.* “Three is Not a Crowd: Efficient Sensitization of TiO2 by a Bulky Trichromic Trisheteroleptic Cycloruthenated Dye.” Chem. Commun2012, 48 (45), 5599-5601. DOI: 10.1039/C2CC00136E

Robson, K. C. D.; Bomben, P. G.; Berlinguette, C. P.* “Cycloruthenated Sensitizers: Improving the Dye-Sensitized Solar Cell with Classical Inorganic Chemistry Principles.” Dalton Trans. 201241 (26), 7814-7829. (Invited Review) DOI: 10.1039/C2DT30825H

Bomben, P. G.; Robson, K. C. D.; Koivisto, B. D.; Berlinguette, C. P.* “Cyclometalated Ruthenium Chromophores for the Dye-Sensitized Solar Cell.” Coord. Chem. Rev2012, 256 (15-16), 1438-1450. (Invited Review) DOI: 10.1016/j.ccr.2012.02.005

Robson, K. C. D.; Koivisto, B. D.; Berlinguette, C. P.* “Derivatization of Bichromic Cyclometalated Ru(II) Complexes with Hydrophobic Substituents.” Inorg. Chem201251 (3), 1501–1507. DOI: 10.1021/ic201768e

Wasylenko, D. W.; Ganesamoorthy, C.; Berlinguette, C. P.* “Interrogation of Electrocatalytic Water Oxidation Mediated by a Cobalt Complex.” Chem. Commun2012, 48 (15), 2107-2109. (Ranked “Very Important Paper”) DOI: 10.1039/C2CC16674G

2011

Ren, Y.; Kan, W. H.; Henderson, M. A.; Bomben, P. G.; Berlinguette, C. P.; Thangadurai, V.; Baumgartner, T.* “External-Stimuli Responsive Photophysics and Liquid Crystal Properties of Self-Assembled “Phosphole-Lipids.” J. Am. Chem. Soc2011, 133 (42), 17014-17026. DOI: 10.1021/ja206784f

Muise, S. S. R.; Severin, H. A.; Koivisto, B. D.; Robson, K. C. D.; Schott, E.; Berlinguette, C. P.* “Regioselective C–H Activation of Cyclometalated Bis-Tridentate Ruthenium Complexes.” Organometallics 201130 (24), 6628-6635. DOI: 10.1021/om200784j

Bomben, P. G.; Gordon, T. J.; Schott, E.; Berlinguette, C. P.* “A Trisheteroleptic Sensitizer that Enables High Power Output in the Dye-Sensitized Solar Cell.” Angew. Chem. Int. Ed2011, 50 (45), 10682-10685. (Ranked “Very Important Paper”; Inside Cover) DOI: 10.1002/anie.201104275

Robson, K. C. D.; Sporinova, B.; Koivisto, B. D.; Schott, E.; Brown, D. G.; Berlinguette, C. P.* “Systematic Modulation of a Cyclometalated Ru(II) Scaffold Bearing a Redox-Active Triphenylamine Constituent.” Inorg. Chem201150 (13), 6019-6028. DOI: 10.1021/ic1025679

Robson, K. C. D.; Sporinova, B.; Koivisto, B. D.; Baumgartner, T.; Yella, A.; Nazeeruddin, M. K.; Grӓtzel, M.;Berlinguette, C. P.* “Design and Development of Functionalized Cyclometalated Ruthenium Chromophores for Light-Harvesting Applications.” Inorg. Chem201150 (12), 5494-5508. DOI: 10.1021/ic200011m

Wasylenko, D. W.; Ganesamoorthy, C.; Borau-Garcia, J; Berlinguette, C. P.* “Electrochemical Evidence for Catalytic Water Oxidation Mediated by a High-Valent Cobalt Complex.” Chem. Commun2011, 47 (14), 4249-4251. DOI: 10.1039/C0CC05522K

Wasylenko, D. W.; Ganesamoorthy, C.; Henderson, M.; Berlinguette, C. P.* “Unraveling the Roles of the Acid Medium, Experimental Probes, and Terminal Oxidant, (NH4)2[Ce(NO3)6], in the Study of a Homogeneous Water Oxidation Catalyst.” Inorg. Chem2011, 50 (8), 3662-3672. DOI: 10.1021/ic2000188

Bomben, P. G.; Theriault, K. D.; Berlinguette, C. P.* “Strategies for Optimizing the Performance of Cyclometalated Ruthenium Sensitizers for Dye-Sensitized Solar Cells.” Eur. J. Inorg. Chem. 2011 (11), 1806-1814. DOI: 10.1002/ejic.201001345

2010

Wasylenko, D. W.; Ganesamoorthy, C.; Henderson, M.; Koivisto, B. D.; Berlinguette, C. P.* “Electronic Modification of the [RuII(tpy)(bpy)OH2]2+ Scaffold: Effects on Catalytic Water Oxidation.” J. Am. Chem. Soc2010132 (45), 16094-16106. DOI: 10.1021/ja106108y

Gordon, T. G.; Szabo, L. D.; Linder, T.; Berlinguette, C. P.; Baumgartner, T.* “Structure-Property Relationships of Acylated Asymmetric Dithienophospholes.” Comp. Rend. Chem. 201013 (8-9), 971-979. DOI: 10.1016/j.crci.2010.04.023

Bomben, P. G.; Koivisto, B. D.; Berlinguette, C. P.* “Cyclometalated Ru(II) Complexes of Type [RuII(N^N)2(C^N)]z: Physicochemical Response to Substituents Installed on the Anionic Ligand.” Inorg. Chem201049 (11), 4960-4971. DOI: 10.1021/ic100063c

Koivisto, B. D.; Robson, K. C. D.; Gordon, T. J.; Baumgartner, T.; Berlinguette, C. P.* “Triphenylamine-Modified Ruthenium Terpyridyine Complexes: Enhancement of Light Absorption by Conjugated Bridging Motifs.” Inorg. Chem201049 (12), 5335. DOI: 10.1021/ic9025427

Sedach, P. S.; Gordon, T. G.; Sayed, S. Y.; Furstenhaupt, T.; Baumgartner, T.; Berlinguette, C. P.* “Solution Growth of Anatase TiO2 Nanowires from Transparent Conducting Glass Substrates.” J. Mat. Chem. 201020 (24), 5063-5069. DOI: 10.1039/C0JM00266F

Wasylenko, D. W.; Ganesamoorthy, C.; Koivisto, B. D.; Berlinguette, C. P.* “Examination of Water Oxidation by Catalysts Containing Cofacial Metal Sites.” Eur. J. Inorg. Chem2010 (20), 3135-3142. (Most accessed article in June 2010) DOI: 10.1002/ejic.201000099

Wasylenko, D. W.; Koivisto, B. D.; Ganesamoorthy, C.; Henderson, M.; Berlinguette, C. P.* “Insight into Water Oxidation by Mononuclear Polypyridyl Ru Catalysts.” Inorg. Chem201049 (5), 2202-2209. DOI: 10.1021/ic902024s

Sui, R.; Young, J.; Berlinguette, C. P.* “Sol-Gel Synthesis of Sn-Doped TiO2 Nanostructures.” J. Mat. Chem. 201020 (3), 498-503. DOI: 10.1039/B915349G

2009

Ghosh, J. P.; Sui, R.; Langford, C. H.*; Achari, G.; Berlinguette, C. P. “A Comparison of Several Nanoscale Photocatalysts in the Degradation of a Common Pollutant Using LEDs and Conventional UV Light.” Wat. Res200943 (18), 4499-4506. DOI: 10.1016/j.watres.2009.07.027

Koivisto, B. D.; Robson, K. C. D.; Berlinguette, C. P.* “Systematic Manipulation of the Light-Harvesting Properties for Tridentate Cyclometalated Ruthenium(II) Complexes.” Inorg. Chem. 200948 (20), 9644-9652. DOI: 10.1021/ic9007137

Bomben, P. G.; Robson, K. C. D.; Sedach, P.; Berlinguette, C. P.* “On the Viability of Cyclometalated Ru(II) Complexes for Light-Harvesting Applications.” Inorg. Chem2009 48 (20), 9631-9643. DOI: 10.1021/ic900653q

Funck, K.; Hilfiger, M. G.; Berlinguette, C. P.; Shatruk, M.; Wernsdorfer, W.; Dunbar, K. R.* “Trigonal-Bipyramidal Metal Cyanide Complexes: A Versitile Platform for the Systematic Assessment of the Magnetic Properties of Prussian Blue Materials.” Inorg. Chem200948 (8), 3438-3452. DOI: 10.1021/ic801990g

2008

Sui, R.; Thangadurai, V.; Berlinguette, C. P.* “Simple Protocol for Generating TiO2 Nanofibers in Organic Media.” Chem. Mat200820 (22), 7022-7030. DOI: 10.1021/cm802091c